Aluminium Isopropoxide
Aluminium Isopropoxide
CAS: 555-31-7
Molecular Formula: C9H21AlO3
Aluminium Isopropoxide - Names and Identifiers
| Name | Aluminium Isopropoxide |
| Synonyms | AIP Aluminium isopropoxi Aluminum Isopropoxide Aluminium Isopropoxide Aluminum propan-2-olate Aluminium iso-Propoxide 2-Propanol, aluminum salt Aluminum trisisopropoxide Aluminum(III)isopropoxide aluminum tripropan-2-olate ALUMINUMISOPROPOXIDE,PRACTICAL Aluminum isopropoxide,AIP, Aluminum isopropylate, Aluminum triisopropoxide |
| CAS | 555-31-7 |
| EINECS | 209-090-8 |
| InChI | InChI=1/C3H8O.Al/c1-3(2)4;/h3-4H,1-2H3;/q;+3 |
| InChIKey | SMZOGRDCAXLAAR-UHFFFAOYSA-N |
Aluminium Isopropoxide - Physico-chemical Properties
| Molecular Formula | C9H21AlO3 |
| Molar Mass | 204.24 |
| Density | 1.035 g/mL at 25 °C (lit.) |
| Melting Point | 128-133 °C (lit.) |
| Boling Point | 125-130 °C (38 mmHg) |
| Flash Point | 46 °C |
| Water Solubility | REACTS |
| Solubility | toluene |
| Vapor Presure | 0.13 hPa (21 °C) |
| Appearance | White crystalline powder |
| Specific Gravity | 1.035 |
| Color | White |
| Exposure Limit | ACGIH: TWA 1 mg/m3 |
| Merck | 14,347 |
| BRN | 3910275 |
| Storage Condition | Store below +30°C. |
| Sensitive | 8: reacts rapidly with moisture, water, protic solvents |
| Explosive Limit | 2%(V) |
| Refractive Index | 1.0346 |
| MDL | MFCD00008870 |
| Physical and Chemical Properties | Character hygroscopic white solid. melting point 128~132 ℃ boiling point 138~148 ℃ relative density 1.035 soluble in ethanol, isopropanol, benzene, toluene, chloroform, carbon tetrachloride and petroleum hydrocarbons. |
| Use | It is an intermediate of hormone drugs such as isophytoalcohol, testosterone, progesterone, and norgestrel, and is also one of the raw materials of aluminate coupling agent |
Aluminium Isopropoxide - Risk and Safety
| Hazard Symbols | F - Flammable |
| Risk Codes | 11 - Highly Flammable |
| Safety Description | S8 - Keep container dry. S16 - Keep away from sources of ignition. S2017/8/16 - |
| UN IDs | UN 3181 4.1/PG 2 |
| WGK Germany | 1 |
| RTECS | BD0975000 |
| TSCA | Yes |
| HS Code | 29051900 |
| Hazard Class | 4.1 |
| Packing Group | II |
| Toxicity | LD50 orally in rats: 11.3 g/kg (Smyth) |
Aluminium Isopropoxide - Upstream Downstream Industry
| Raw Materials | Aluminum Isopropanol |
| Downstream Products | 16-17A-Epoxyprogesterone Miconazole nitrate Progesterone |
Aluminium Isopropoxide - Nature
Open Data Verified Data
hygroscopic white solid. The melting point was 128-132 °c. Boiling Point (1333Pa) 138~148. The relative density was 1. 035. Soluble in ethanol, isopropanol, benzene, toluene, chloroform, carbon tetrachloride and petroleum hydrocarbons. Decomposition in water.
Last Update：2025-06-10 22:55:16
Aluminium Isopropoxide - Preparation Method
Open Data Verified Data
The reaction is carried out by heating isopropyl alcohol and aluminum in the presence of the catalyst aluminum trichloride, and after the aluminum is dissolved, vacuum distillation is carried out to obtain the finished product.
Last Update：2022-01-01 10:54:11
Aluminium Isopropoxide - Introduction
Reacts with water and is soluble in ethanol, isopropanol, benzene, toluene, chloroform and carbon tetrachloride. Easy to absorb moisture and decompose into aluminum hydroxide and isopropanol in contact with water.
Last Update：2022-10-16 17:26:19
Aluminium Isopropoxide - Application
Open Data Verified Data
This product can be used as the raw material of dehydrating agent, catalyst and waterproofing agent, and can also be used in pharmaceutical industry.
Last Update：2025-08-19 16:24:40
Aluminium Isopropoxide - Safety
Open Data Verified Data
- This product is toxic. The LD50 for rats was 11.3g/kg. The equipment should be sealed, and the operator should wear protective equipment. The workshop should be ventilated.
- The package was sealed with an iron drum. Waterproof and moisture-proof. According to the provisions of the storage and transportation of toxic chemicals.
Last Update：2022-01-01 10:54:11
Aluminium Isopropoxide - Reference Information
| LogP | 0.05 at 25℃ |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Introduction | aluminum isopropoxide, also known as isopropyl aluminum oxide, English name is aluminum isopropoxide, abbreviated as AIP. When it is first produced, it is a colorless viscous liquid, which condenses into a solid state in 5-10 days. Aluminum isopropoxide on the market is mostly white translucent block, cylindrical small solid or powder, soluble in isopropanol, ethanol, toluene, benzene, carbon tetrachloride, chloroform and other organic solvents (heated to 70 ° C or more easily dissolved), water decomposition, strong water absorption, easy to decompose into aluminum hydroxide and isopropanol. |
| preparation method | is obtained by reacting metallic aluminum with isopropanol under the catalysis of mercuric chloride. In a 1L flask equipped with a reflux condenser and a calcium chloride drying tube were placed 1mol of aluminium wire or aluminium flakes, and 300ml of anhydrous isopropanol was obtained by distillation using industrial isopropanol with the addition of 5% of sodium by mass. And 0.5g of hgcl2. Heating to reflux was continued, and when boiling started, 2ml of carbon tetrachloride was added via the condenser, and the heating was continued to guide the sudden start of hydrogen evolution. Heat sources were removed and sometimes required cooling. When the violent reaction is calm, continue to boil until the aluminum is completely reacted (about 6~12h), after the solvent is distilled out, the residue is distilled under reduced pressure, the product was collected at a boiling point of 130-140 °c/933Pa(7mmHg). The yield was 90% ~ 95%. The product is usually cured after 1 to 2 days, and can be stored in a glass bottle sealed with paraffin. |
| aluminum isopropoxide hydrolysis | aluminum isopropoxide hydrolysis is one of the methods to produce pseudo boehmite, aluminum isopropoxide is hydrolyzed to obtain pseudoboehmite and isopropyl alcohol (isopropyl alcohol can be recovered), and pseudoboehmite can obtain high purity pseudoboehmite by one-time distillation. High purity and high purity alumina can be obtained by calcination of high purity pseudo boehmite. This process route is a formal process route for the preparation of alumina by alcoholysis. |
| Use | used as a reducing agent, a strong dehydrating agent used as a raw material for a dehydrating agent, a catalyst, and a water repellent. can be used as a positive grade material for lithium batteries. as a reducing agent and a strong dehydrating agent, it is an intermediate of hormone drugs such as isophytoalcohol, testosterone, progesterone, and norgestrel, and is also one of the raw materials of aluminate coupling agent, which is used as a raw material of a dehydrating agent, a catalyst, and a water repellent. Can be used for lithium battery positive materials. reducing agent, strong dehydrating agent. Organic Synthesis. Paint, paint composition. Fabric sizing. |
| production method | is obtained by the reaction of isopropanol and aluminum under the catalysis of alumina. Raw material consumption quota: isopropyl alcohol 1255kg/t, aluminum 166kg/t. |
| category | toxic substances |
| toxicity grade | low toxicity |
| Acute toxicity | oral-rat LD50: 11300 mg/kg |
| flammability hazard characteristics | flammable; Combustion-induced irritating smoke |
| storage and transportation characteristics | warehouse ventilation and low temperature drying |
| extinguishing agent | dry powder, foam, sand, carbon dioxide |
| Occupational Standard | TWA 2 mg (aluminum)/m3 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-10 22:29:15
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View History
Aluminium Isopropoxide
94086-65-4
226-962-3
4963-91-1
丝软化剂
2832-45-3
3-(1-Methylethyl)phenol
81024-43-3
CIS-1.3-DICHLOROPROPENE SOLUTION 100UG/ML IN METHANOL 1ML
83792-48-7
94086-65-4
226-962-3
4963-91-1
丝软化剂
2832-45-3
3-(1-Methylethyl)phenol
81024-43-3
CIS-1.3-DICHLOROPROPENE SOLUTION 100UG/ML IN METHANOL 1ML
83792-48-7
Raw Materials for Aluminium Isopropoxide
Downstream Products for Aluminium Isopropoxide